The p-Block Elements Questions and Answers Part-16

1. Name of the structure of silicates in which three oxygen atoms of \[\left[SiO_{4}\right]^{4-}\]  are shared
a) Pyrosilicate
b) Sheet silicate
c) Linear chain silicate
d) Three dimensional silicate

Answer: b
Explanation:
q151

2. When \[PbO_{2}\]  reacts with conc. \[HNO_{3}\]   the gas evolved is
a) \[NO_{2}\]
b) \[O_{2}\]
c) \[N_{2}\]
d) \[N_{2}O\]

Answer: b
Explanation:
q152

3. The species present in solution when \[CO_{2}\] is dissolved in water are
a) \[CO_{2},H_{2}CO_{3},HCO_3^-,CO_3^{2-}\]
b) \[H_{2}CO_{3},CO_3^{2-}\]
c) \[CO_3^{2-},HCO_3\]
d) \[CO_{2},H_{2}CO_{3}\]

Answer: a
Explanation:
q153

4. On addition of excess of sodium hydroxide solution to stannous chloride solution, we obtain :
a) \[Sn\left( OH\right)_{2}\]
b) \[SnO_{2}.H_{2}O\]
c) \[Na_{2}SnO_{2}\]
d) None of these

Answer: d
Explanation:
q154

5. Lead pipes are readily corroded by
a) \[H_{2}SO_{4}\]
b) HCl
c) \[CH_{3}COOH\]
d) pure water

Answer: c
Explanation: Lead pipes are readily corroded by water containing organic acids

6. A salt which gives \[CO_{2}\]  with hot \[H_{2}SO_{4}\]  and also decolourises acidified \[KMnO_{4}\]  on warming is
a) bicarbonate
b) carbonate
c) oxalate
d) acetate

Answer: c
Explanation:
q156

7. Which halide is least stable and has doubtful existence
a) \[CI_{4}\]
b) \[GeI_{4}\]
c) \[SnI_{4}\]
d) \[PbI_{4}\]

Answer: d
Explanation: In nature Pb4+ is strong oxidant and I- is strong reductant. Hence PbI4 cannot exist.

8. \[R_{3}SiCl\]  on hydrolysis forms
a) \[R_{3}SiOH\]
b) \[R_{3}Si -O-SiR_{3}\]
c) \[R_{2}Si = O\]
d) None of these

Answer: b
Explanation:
q158

9. Which melts in boiling water ?
a) Gun metal
b) Wood’s metal
c) Monel metal
d) Bell metal

Answer: b
Explanation: Wood metal m.p.t. 70ºC .

10. Incomplete combustion of petrol or diesel oil in automobile engines can be best detected by testing the fuel gases for the presence of
a) \[CO + H_{2}O\]
b) CO
c) \[NO_{2}\]
d) \[SO_{2}\]

Answer: b
Explanation: The exhaust of auto gives CO due to incomplete combustion of petrol or diesel.