Solutions Questions and Answers Part-4

1. Which of the following is not correct for ideal solution?
a) \[\triangle S_{mixing}=0\]
b) \[\triangle V_{mixing}=0\]
c) \[\triangle H_{mixing}=0\]
d) It obeys Raoult's law

Answer: a
Explanation:
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2. Which of the following does not show positive deviation from Raoult's law?
a) Benzene-Chloroform
b) Benzene-Acetone
c) Benzene-Ethanol
d) Benzene-Carbon tetrachloride

Answer: a
Explanation: Benzene + chloroform, show negative deviation.

3. Identify the mixture that shows positive deviation from Raoult's law
a) \[CHCl_{3}+\left(CH_{3}\right)_{2}CO\]
b) \[\left(CH_{3}\right)_{2}CO+C_{6}H_{5}NH_{2}\]
c) \[CHCl_{3}+C_{6}H_{6}\]
d) \[\left(CH_{3}\right)_{2}CO+CS_{2}\]

Answer: d
Explanation: CH3COCH3 + CS2

4. Azeotropic mixture of HCl and \[H_{2}O\]   has
a) 48% HCl
b) 22.2% HC
c) 36% HCl
d) 20.2% HCl

Answer: d
Explanation: Azeotrope of HCl + H2O contains 20.2% HCl

5. Which of the following is not a colligative property?
a) Depression in freezing point
b) Elevation of boiling point
c) Osmotic pressure
d) Modification of refractive index

Answer: d
Explanation: Modification of refractive index is not a colligative property

6. Which of the following is a colligative property?
a) Change in free energy
b) Change in pressure
c) Heat of vapourisation
d) Osmotic pressure

Answer: d
Explanation: Osmotic pressure

7. Which of the following colligative properties can provide molar mass of proteins (or polymers or colloids) with greatest precision?
a) Depression in freezing point
b) Osmotic pressure
c) Relative lowering of vapour pressure
d) Elevation of boiling point

Answer: b
Explanation: Osmotic pressure

8. Isotonic solutions have same
a) molar concentration
b) molality
c) normality
d) None of these

Answer: a
Explanation: Isotonic solutions have same molar concentration at given temperature provided the Van't Hoff factor (i) is same

9. When mango is placed in dilute aqueous solution of hydrochloric acid, it
a) shrinks
b) swells
c) bursts
d) Nothing happens

Answer: b
Explanation: Mango swells due to osmosis.

10.As a result of osmosis, the volume of the solution
a) gradually decreases
b) gradually increases
c) is not affected
d) Any of the three

Answer: b
Explanation: Increases