1. Which of the following is not correct for ideal solution?
a) \[\triangle S_{mixing}=0\]
b) \[\triangle V_{mixing}=0\]
c) \[\triangle H_{mixing}=0\]
d) It obeys Raoult's law
Explanation:
2. Which of the following does not show positive deviation
from Raoult's law?
a) Benzene-Chloroform
b) Benzene-Acetone
c) Benzene-Ethanol
d) Benzene-Carbon tetrachloride
Explanation: Benzene + chloroform, show negative deviation.
3. Identify the mixture that shows positive deviation from
Raoult's law
a) \[CHCl_{3}+\left(CH_{3}\right)_{2}CO\]
b) \[\left(CH_{3}\right)_{2}CO+C_{6}H_{5}NH_{2}\]
c) \[CHCl_{3}+C_{6}H_{6}\]
d) \[\left(CH_{3}\right)_{2}CO+CS_{2}\]
Explanation: CH3COCH3 + CS2
4. Azeotropic mixture of HCl and \[H_{2}O\] has
a) 48% HCl
b) 22.2% HC
c) 36% HCl
d) 20.2% HCl
Explanation: Azeotrope of HCl + H2O contains 20.2% HCl
5. Which of the following is not a colligative property?
a) Depression in freezing point
b) Elevation of boiling point
c) Osmotic pressure
d) Modification of refractive index
Explanation: Modification of refractive index is not a colligative property
6. Which of the following is a colligative property?
a) Change in free energy
b) Change in pressure
c) Heat of vapourisation
d) Osmotic pressure
Explanation: Osmotic pressure
7. Which of the following colligative properties can provide
molar mass of proteins (or polymers or colloids) with greatest
precision?
a) Depression in freezing point
b) Osmotic pressure
c) Relative lowering of vapour pressure
d) Elevation of boiling point
Explanation: Osmotic pressure
8. Isotonic solutions have same
a) molar concentration
b) molality
c) normality
d) None of these
Explanation: Isotonic solutions have same molar concentration at given temperature provided the Van't Hoff factor (i) is same
9. When mango is placed in dilute aqueous solution of
hydrochloric acid, it
a) shrinks
b) swells
c) bursts
d) Nothing happens
Explanation: Mango swells due to osmosis.
10.As a result of osmosis, the volume of the solution
a) gradually decreases
b) gradually increases
c) is not affected
d) Any of the three
Explanation: Increases